弹性体材料的橡胶定义

如题所述

首先根据美国测量与材料协会(ASTM)颁布的ASTM D1566-07a标准,“Standard Terminology Relating to Rubber(橡胶相关标准术语学)”来辨析一下这两个词的定义及其涵盖范围。  rubber—material that is capable of recovering from large deformations quickly and forcibly, and can be, or already is, modified to a state in which it is essentially insoluble (but can swell) in boiling solvent, such as benzene, methyl ethyl ketone, or ethanol-toluene azeotrope.  DISCUSSION—A rubber in its modified state, free of diluents, retracts within 1 min to less than 1.5 times its original length after being stretched at room temperature (18 to 29°C) to twice its length and held for 1 min before release.  以上就是该标准对于橡胶(rubber)的定义。从这个定义包含两层含义:(1)是说明了橡胶材料的力学特征——能够从大变形迅速而强烈的回复;(2)是说明了橡胶可以被改性(实际上就是化学交联)到不溶解、可溶胀的状态——能够被改性(或已经被改性)至一种不能被沸腾溶剂(如苯、甲基乙基酮、乙醇-甲苯共沸物)溶解(但可以溶涨)的状态。  该定义还对改性后的橡胶(不含稀释剂,可能是指增塑剂)的力学性能特点做了更明确的解释——在(18-29C)温度范围下被拉伸至本身原始长度的2倍并保持1min后撤出外力,能够在1min内回缩到小于其1.5倍原长。

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